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郑煜       

 
办公电话:
Office Address:化工楼2221A
E-Mail:zhengy@njfu.edu.cn
 
个人简况

安徽蚌埠人,博士学历,研究生导师。20182月博士毕业于德国马尔堡大学。博士期间主要从事唯金属中心手性八面体配合物的合成及其在不对称催化方面的应用。同年4月加入北京大学化学学院席振峰院士/张文雄教授课题组从事博士后研究工作。博士后期间主持中国博士后科学基金面上项目1项。202012月全职加入南京林业大学化学工程学院。近年来在Journal of the American Chemical SocietyChemistry-A European Journal等国际权威刊物上发表SCI 论文十余篇。

工作经历
个人简况

安徽蚌埠人,博士学历,研究生导师。20182月博士毕业于德国马尔堡大学。博士期间主要从事唯金属中心手性八面体配合物的合成及其在不对称催化方面的应用。同年4月加入北京大学化学学院席振峰院士/张文雄教授课题组从事博士后研究工作。博士后期间主持中国博士后科学基金面上项目1项。202012月全职加入南京林业大学化学工程学院。近年来在Journal of the American Chemical SocietyChemistry-A European Journal等国际权威刊物上发表SCI 论文十余篇。

研究方向

绿色合成化学

林源活性物质的化学合成与修饰

不对称合成


学术成果

1. Zheng, Y.#; Cao, C.-S.#; Ma, W.#; Chen, T.; Wu, B.; Yu, C.; Huang, Z.; Yin, J.; Hu, H.-S.*; Li, J.; Zhang, W.-X.*; Xi, Z. 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins. J. Am. Chem. Soc. 2020142, 10705–10714. (#equal contribution).
2. Zheng, Y.; Tan, Y.; Harms, K.; Marsch, M.; Riedel, R.; Zhang, L.; Meggers, E.* Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis. J. Am. Chem. Soc. 2017139, 4322–4325 (highlighted in Synfacts 2017, 0625).3. Zheng, Y.; Zhang, L.; Meggers, E.* Catalytic Enantioselective Synthesis of Key Propargylic Alcohol Intermediates of the Anti-HIV Drug Efavirenz. Org. Process Res. Dev201822, 103–107 (highlighted in Synfacts 2018, 0343).
4. Zheng, Y.; Harms, K.; Zhang, L.*; Meggers, E.* Enantioselective Alkynylation of 2-Trifluoroacetyl Imidazoles Catalyzed by Bis-Cyclometalated Rhodium(III) Complexes Containing Pinene-Derived Ligands. Chem. - Eur. J. 201622, 11977–11981 (highlighted in Synfacts 2016, 1156).
5. Xue, M.*; Zheng, Y.; Hong, Y.; Yao, Y.; Xu, F.*; Zhang, Y.; Shen, Q. Catalytic Addition of Amines to Carbodiimides by Bis(β-diketiminate)lanthanide(II) Complexes and Mechanistic StudiesDalton Trans201544, 20075–20086.
6. Zheng, Y.; Jiao, R.; Shen, X.; Xue, M.*; Yao, Y.; Zhang, Y.; Shen, Q.* Bis(beta-diketiminato) lanthanide amides: synthesis, structure and catalysis for the polymerization of L-lactide and epsilon-caprolactone. Appl. Organomet. Chem. 201428, 461–470.
7. Huang, Z.; Zheng, Y.; Zhang, W.-X.; Ye, S.*; Deng, L.*; Xi, Z.* Dinickelaferrocene: Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back Donation from Fe. Angew. Chem., Int. Ed202059, 14394–14398.
8. Hu, N.; Jung, H.; Zheng, Y.; Lee, J.; Zhang, L.; Ullah, Z.; Xie, X.; Harms, K.; Baik, M.-H.*; Meggers, E.* Catalytic Asymmetric Dearomatization by Visible-Light-Activated [2+2] Photocycloaddition. Angew. Chem., Int. Ed. 201857, 6242–6246.
9. Chen, S.; Zheng, Y.; Cui, T.; Meggers, E.; Houk, K. N.* Arylketone πConjugation Controls Enantioselectivity in Asymmetric Alkynylations Catalyzed by Centrochiral Ruthenium Complexes. J. Am. Chem. Soc. 2018140, 5146−5152.
10. Luo, S.; Zhang, X.; Zheng, Y.; Harms, K.; Zhang, L.; Meggers, E.* Enantioselective Alkynylation of Aromatic Aldehydes Catalyzed by a Sterically Highly Demanding Chiral-at-Rhodium Lewis Acid. J. Org. Chem. 201782, 8995−9005.
11. Chen, S.; Hong, Y.; Liu, Y.; Xue, M.*; Zheng, Y.; Shen, Q. Synthesis and Properties of Sodium and Europium(Ⅲ) Cryptates Incorporating the 4,4'-Substituted-2,2'-bipyridine Units. Chin. J. Org. Chem. 201737, 1198–1204.
12. Liu, Q.; Hong, Y.; Zheng, Y.; Xue, M.* Bis(β-diketiminato) Lanthanide(II) Complexes-Catalyzed Hydrophosphonylation of Aldehydes/ketones and Diethylphosphite. Chin. J. Org. Chem. 201636, 2168–2174.
13. Wang, C.; Zheng, Y.; Huo, H.; Röse, P.; Zhang, L.; Harms, K.; Meggers, E.* Merger of Visible Light Induced Oxidation and Enantioselective Alkylation with Chiral Iridium Catalyst. Chem. - Eur. J. 201521, 7355–7359.
14. Hong, Y.; Zheng, Y.; Xue, M.*; Yao, Y.; Zhang, Y.; Shen, Q.* Phenylene-Bridged β-Ketoiminate Dilanthanide Aryloxides: Synthesis, Structure, and Catalytic Activity for Addition of Amines to Carbodiimides. Z. Anorg. Allg. Chem. 2015641, 1230–1237.

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