47. Fei Cong, Guo-Quan Sun, Si-Han Ye, Rui Hu, Weidong Rao, and Ming Joo Koh*A Bimolecular Homolytic Substitution-Enabled Platform for Multicomponent Cross-Coupling of Unactivated Alkenes. J. Am. Chem. Soc. 2024, 146, 10274−10280.
46. Jichao Chen, Zhen Liu, Andrés Felipe León Rojas, Weidong Rao,* and Philip Wai Hong Chan*. Gold-Catalyzed Double Spirocyclization of 3‑Ene-1,7-diyne Esters to Dispiroheterocycles. Org. Lett. 2024, 26, 2635−2640. 45. Zeliang Wang, Jichao Chen, Lei Yu, Chunyu Zhang, Weidong Rao,* and Philip Wai Hong Chan*. Gold-Catalyzed Cascade Cycloisomerization of 3‑Allyloxy-1,6-diynes to Cyclopropyl- and Cyclobutyl-Fused Benzofurans and Chromen-3a(1H)‑ols. Org. Lett. 2024, 26, 2635−2640. 44. Yuling Teng, Xiangdong Yu, Dandan Shang, Zeliang Wang, and Weidong Rao*. Brønsted Acid-Catalyzed Dehydrative Nazarov-type Cyclization of CF3‑Substituted 3‑Indolylallyl Alcohols: Divergent Synthesis of 1‑Trifluoromethylated Cyclopenta[b]indoles. J. Org. Chem. 2024, 89, 1147−1159. 43. Zhen Liu, Mitch Mathiew, Jichao Chen, Xiangdong Yu, Dandan Shang, Javey Khiapeng Tan, Philip Wai Hong Chan* and Weidong Rao*. Gold catalyzed spirocyclization of 1-ene-4,9- and 3-ene-1,7-diyne esters to azaspiro[4.4]nonenones and azaspiro[4.5]decadienones. Org. Chem. Front. 2024, 11, 761−768. 42. Li Feng, Yuling Teng, Xiangdong Yu, Zeliang Wang, and Weidong Rao*. Brønsted Acid-Catalyzed Dehydrative Nazarov-Type Cyclization/C2−N1 Cleavage Cascade of Perfluoroalkylated 3‑Indolyl(2-benzothienyl)methanols. Org. Lett. 2023, 25, 4956−4961. 41. Rui Feng, Fei Liu, Yan Wang, Shu Xu, Wuzhang Liu, Siwei Qiao, Songtao Liu, Yu Chen, Xu Feng, Qizhi Wang,* Weidong Rao*. The discovery of 3-fluoroalkyl indoles as potential antifungal agents to control tomato gray mold caused by Botrytis cinerea. Phytochemistry Letters 2023, 55, 175−183. 40. Qing Bao, Jichao Chen, Zhen Liu and Weidong Rao*. Direct construction of biaryl-bridged 8–11 membered N-heterocycles via gold(I)-catalyzed intramolecular [4 + 2] benzannulation of N-tethered diynyl benzaldehydes, Org. Chem. Front. 2023, 10, 3280−3287. 39. Dandan Shang, Rui Hu,Qing Bao, Jichao Chen, Lei Yu, Philip Wai Hong Chan* and Weidong Rao*, PtI4-catalyzed oxidative and hydrogenative dearomative [3 + 2] cycloaddition of 1H-indole N-tethered o-alkynylbenzaldehydes, Org. Chem. Front., 2023, 10, 140-149.
38. Chen, J.; R.; Q.; Shang, D.; Yu, L.; Chan, P. W. H.;* Rao, W.* Ligand-controlled chemoselectivity in gold-catalyzed cascade cyclization of 1,4-diene-tethered 2-alkynylbenzaldehydes, Org. Chem. Front., 2022, 9, 6520-6529. 37. Hu, R.; Chen, J.; Wang, Z.; Shang, D.; Yu, L.;Chan, P. W. H.*,Rao, W.* THF-Enabled PtBr2-Catalyzed Desymmetric Hydrogenative [3+2] Cycloaddition of 2-Alkynylbenzaldehyde-Tethered Cyclohexadienones,Organic Chemistry Frontiers, 2022, 9, 3577-3584.
36. Baratay, C. A.; Li, W.; Mathiew, M.; Yu, L.; Kyne, S, H.; Rao, W.*;Chan, P. W. H.* Gold- and Bronsted Acid-Catalysed Deacyloxylative Cycloaromatisation of 1,6-Diyne Esters to 11H-Benzo[a]fluorenes and 13H-Indeno[1,2-1]phenanthrenes, Adv. Synth. Catal. 2022, 364, 1313-1318. 35. Sang, J.; Feng, L.; Hu, R.; Chen, J.;Shang, D.; Bao, Q.; Rao, W.* Sc(OTf)3-Catalyzed C2-Selective Cyanation/Defluorination Cascade of Perfluoroalkylated 3-Indolylmethanols and Application to the Synthesis of 3-Fluoro(perfluoroalkyl)-β-carbolines, Org. Lett. 2021, 23, 7666-7671. 34. An, D.; Sang J.; Hu, R.; Chen, J.; Feng, L.; Rao, W.* Synthesis of 2-Phosphoryl-3-monofluorovinylindoles under Catalyst- and Additive-free Conditions, Adv. Synth. Catal. 2021, 363, 3496-3501. 33. Chen, X.; Rao, W.; Yang, T.;* Koh, M. J.* Alkyl Halides as Both Hydride and Alkyl Sources in Catalytic Regioselective Reductive Olefin Hydroalkylation, Nature Commun. 2020, 11, 5857. 32. Yang, T.; Chen, X.; Rao, W.; Koh, M. J. Broadly Applicable Directed Catalytic Reductive Difunctionalization of Alkenyl Carbonyl Compounds, Chem 2020, 6, 738-751. 31. An, D.; Miao, X.; Ling, X.; Chen, X.; Rao, W.* DBSA-Catalyzed Regioselective Dehydrative Friedel-Crafts Arylation of CF3-Containing 3-Indolyl(2-thiophenyl)methanols with 2-Substituted Indoles in Water, Adv. Synth. Catal. 2020, 362, 1514-1524. 30. Chen, X.; Zhou, Y.; Jin, J.; Farshadfar, K.; Ariafard, A.*; Rao, W.*; Chan, P. W. H.* Gold Catalyzed Cyclopropanation/[5+3] Cycloaddition of 1,4,9-and 1,4,10-Allenenynes to Bicyclo[3.3.1]nonane Derivatives, Adv. Synth. Catal. 2020, 362, 1084-1095. 29. Zhong, J.; Hu, R.; Sang, J.; Rao, W.* Gold(I)-Catalyzed Intramolecular [4+2] Cycloaddition of ortho-(N-tethered 1,6-diynyl)benzaldehydes to 3,4-dihydrobenzo[f]isoquinolin-1(2H)-ones, Tetrahedron Lett. 2020, 61, 152200. 28. Chen, X.;# Ling, X.;# An, D.; Rao, W.* Gold-Catalyzed Sequential Cycloisomerization of 1,3,9-Ene-allene-ynes to Fused Spirocarbocycles. Eur. J. Org. Chem. 2020, 32, 5227-5233. 27. Zhou, Y.; Chen, X.; Ling, X.; Rao, W.* Catalyst- and additive-free Baeyer-Villiger-type oxidation of α-iodocyclopentenones to α-pyrones: using air as the oxidant, Green Chem. 2019, 21, 5611-5615. 26. Ling, Y.; An, D.; Zhou, Y.; Rao, W.* Ga(OTf)3-catalyzed temperature-controlled regioselective Friedel-Crafts alkylation of trifluoromethylated 3-indolylmethanols with 2-substituted indoles: divergent synthesis of trifluoromethylated unsymmetrical 3,3′-and 3,6′-bis(indolyl)methanes, Org. Lett. 2019, 21, 3396-3401. 25. Zhou, Y.; Chen, X.; Yin, D.; Ling, Y.; Wang, S.; Zhang, X.; Rao, W.* Gold-catalyzed cycloisomerization/halogenation sequence of 1,3-enyne esters with NXS: efficient synthesis of 5-bromo/iodo cyclopentenones, Eur. J. Org. Chem., 2019, 999-1007. 24. Chen, X.; Zhou, Y.; Hong, M.; Ling, Y.; Yin, D.; Wang, S.; Zhang, X.;* Rao, W.* Gold(I)-catalyzed tandem cycloisomerization and fluorination of 1,3(4)-enyne esters with NFSI: one-pot assembly of 5-fluoro-cyclopentenones, Adv. Synth. Catal. 2018, 360, 3700-3708. 23. Chen, C.; Chen, X.; Zhang, X.; Wang, S.; Rao, W.;* Chan, P. W. H.* Gold-catalyzed dehydrogenative cycloisomerization of 1,4-enyne esters to 3,5-disubstituted phenol derivatives, Adv. Synth. Catal. 2017, 359, 4359-4368. 22. Zou, Y.; Chen, C.; Chen, X.; Zhang, X.;* Rao, W.* Silica gel mediated Friedel-Crafts alkylation of 3-indolylmethanols with indoles: synthesis of unsymmetrical bis(3-in-dolyl)methanes, Eur.J.Org.Chem. 2017, 16, 2266-2271. 21. Zhang, X.;*Li, P.; Lyu, C.; Yong, W.; Li, J.; Pan, X.; Zhu, X.; Rao, W.* Palladium-catalyzed one-pot synthesis of via 1H-indole-3-sulfonates generated in situ from 2-alkynyl arylazides and sulfonic acids ” Adv. Synth. Catal. 2017, 359, 4147-4152. 20. Zhang, X.;* Li, P.; Lyu, C.; Yong, W.; Li, J.; Zhu, X.; Rao, W* Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids, Org. Biomol. Chem. 2017, 15, 6080-6083. 19. Chen, C.; Zou, Y.; Chen, X.; Zhang, X.; Rao, W.;* Chan, P. W. H. * Gold-catalyzed tandem 1,3-migration/double cyclopropanation of 1-ene-4,n-diyne esters to tetracyclodecene and tetracycloundecene derivatives, Org. Lett. 2016, 18, 4730-4733. 18. Rao, W.;* Boyle, J. W.; Chan, P. W. H.*, Gold-catalyzed sequential cyclization of 1-en-3,9-Diyne esters to partially hydrogenated 3H-dicyclopenta[a,b]naphthalenes, Chem. Eur. J. 2016, 22, 6532-6536. 17. Zhang, X.;* Sun, X.; Fan, H.; Lyu, C.; Li, P.; Zhang, H.; Rao, W.*.Gold-catalyzed formation of indole derivatives from 2-alkynyl arylazides and oxygen-containing heterocycles, RSC Adv. 2016, 6, 56319-56322. 16. Zhang, X.;* Sun, X.; Fan, H.; Li, P.; Lyu, C.; Rao, W.* Gold-catalyzed chemoselective synthesis of heterocycles from3-(2-azidophenyl)prop-2-yn-1-ols and aldehydes, Eur. J. Org. Chem. 2016, 4265-4268. 15. Rao, W.; Susanti, D.; Ayers, B. J.; Chan, P. W. H.* Ligand-controlled product selectivity in Gold-catalyzed double cycloisomerization of 1,11-dien-3,9-diyne benzoates, J. Am. Chem. Soc. 2015, 137, 6350-6355. 14. Rao, W.; Sally, Berry, S. N.; Chan, P. W. H.* Gold-catalyzed cycloisomerization of 1,6,8-dienyne carbonates and esters to cis-cyclohepta-4,8-diene-fused pyrrolidines, Chem. Eur. J. 2014, 20, 13174-13180. 13. Rao, W.; Chan, P. W. H.* Gold-catalyzed [2+2+1] cycloaddition of 1,6-diyne carbonates and esters with aldehydes to 4-(cyclohexa-1,3-dienyl)-1,3-dioxolanes, Chem. Eur. J. 2014, 20, 713-718. 12. Rao, W.; Koh, M. J.; Li, D.; Hirao, H.;* Chan, P. W. H.* Gold-catalyzed cycloisomerization of 1,6-diyne carbonates and esters to 2,4a-dihydro-1H-fluorenes, J. Am. Chem. Soc. 2013, 135, 7926-7932. 11. Rao, W.; Sally, Koh, M. J.; Chan, P. W. H.* Gold-catalyzed cycloisomerization of 1,7-enyne esters to structurally diverse cis-1,2,3,6-tetrahydropyridin-4-yl ketones, J. Org. Chem. 2013, 78, 3183-3195. 10. Rao, W.; Koh, M. J.; Kothandaraman, P.; Chan, P. W. H.* Gold-catalyzed cycloisomerization of 1,7-diyne benzoates to indeno[1,2-c]azepines and azabicyclo[4.2.0]octa-1(8),5-dines, J. Am. Chem. Soc. 2012, 134, 10811-10814. 9. Rao, W.; Susanti, D.; Chan, P. W. H.* Gold-Catalyzed Tandem 1,3-Migration/[2+2] Cycloaddition of 1,7-Enyne Benzoates to Azabicyclo[4.2.0]oct-5-enes, J. Am. Chem. Soc. 2011, 133, 15248-15251. 8. Kothandaraman, P.; Rao, W.; Foo, S. J.; Chan, P. W. H.* Gold-catalyzed cycloisomerization reactions of 2-tosylaminophenylprop-1-yn-3-ols as a versatile approach for indole synthesis, Angew. Chem. Int. Ed. 2010, 49, 4619-4623. 7. Rao, W.; Kothandaraman, P.; Koh, C. B.; Chan, P. W. H.* Copper(II) Triflate Catalyzed Intramolecular Hydroamination of Homoallylic Aminoalcohols as an Expedient Route to Trans-2,5-Dihydro-1H-pyrroles and 1,2-Dihydroquinolines, Adv. Synth. Catal. 2010, 352, 2521-2530. 6. Rao, W.; Chan, P. W. H.* Unexpected Iron(III) Chloride-Catalysed Dimerisation of 1,1,3-Trisubstituted-prop-2-yn-1-ols as an Expedient Route to Highly Conjugated Indenes, Org. Biomol. Chem. 2010, 8, 4016-4025. 5. Rao, W.; Zhang, X.; Sze, E. M. L. Chan, P. W. H.*Ytterbium(III) Triflate-Catalyzed Amination of 1-Cyclopropylprop-2-yn-1-ols as an Expedient Route to Conjugated Enynes, J. Org. Chem. 2009, 74, 1740-1743. 4. Rao, W.; Chan, P. W. H.*Gold- and Silver-Catalyzed Tandem Amination/Ring Expansion of Cyclopropylmethanols with Sulfonamides as an Expedient Route to Pyrrolidines, Chem. Eur. J. 2008, 14, 10486-10495. 3. Rao, W.; Chan, P. W. H.* Gold-Catalysed Allylic Alkylation of Aromatic and Heteroaromatic Compounds with Allylic Alcohols, Org. Biomol. Chem. 2008, 6, 2426-2433. 2. Rao, W.; Tay, A. H. L.; Goh, P. J.; Choy, J. M. L.; Ke, J. K.; Chan, P. W. H.* Iodine-Catalyzed Allylation of 1,3-Dicarbonyl Compounds with Allylic Alcohols at Room Temperature, Tetrahedron Lett. 2008, 49, 122-126. 1. Rao, W.; Chan, P. W. H.* Stereoselective Synthesis of Trans-a-ketohydrazones from Silyl Enol Ethers Mediated by Iodobenzene Diacetate, Tetrahedron Lett. 2007, 48, 3789-3792. 授权发明专利： 15. 饶卫东、包晴，一种联芳基桥联八元或九元或十元含氮杂环类化合物及其合成方法， ZL202211236168.3. 14. 饶卫东、陈继超、滕玉玲、冯丽，一种环丙烷稠合的6/7/7苯并氧桥多环类化合物及其合成方法，ZL202210854077.X. 13.饶卫东、胡睿、王泽梁、陈继超，一种苯环稠合的5/6/7/6四环化合物及其合成方法，ZL 202210188887.6。
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