张小祥，男，江苏江都人，九三学社社员，教授，博士生导师。2011年毕业于新加坡南洋理工大学(Nanyang Technological University)获博士学位；2011年至2012年在法国巴黎综合理工学院(école Polytechnique)从事博士后研究。2013年进入南京林业大学化学工程学院精细化工系从事教学科研工作。入选江苏省“双创博士”（境外名校类创新）、江苏省高校“青蓝工程”优秀青年骨干教师、江苏省“科技副总”、扬州市“绿扬金凤计划”优秀博士、校“人才培养计划”。作为项目负责人先后承担国家自然科学基金、江苏省自然科学基金青年项目、面上项目以及企业横向项目等。主要从事有机合成化学、功能助剂的研制与开发（如萘系磺酸盐系列缩合物分散剂）。近年来，授权发明专利多项，在Organic Chemistry Frontiers、Organic Letters、Advanced Synthesis & Catalysis、《有机化学》、《现代农药》等国内外刊物上发表30多篇论文。

张小祥，男，江苏江都人，九三学社社员，教授，博士生导师。2011年毕业于新加坡南洋理工大学(Nanyang Technological University)获博士学位；2011年至2012年在法国巴黎综合理工学院(école Polytechnique)从事博士后研究。2013年进入南京林业大学化学工程学院精细化工系从事教学科研工作。入选江苏省“双创博士”（境外名校类创新）、江苏省高校“青蓝工程”优秀青年骨干教师、江苏省“科技副总”、扬州市“绿扬金凤计划”优秀博士、校“人才培养计划”。作为项目负责人先后承担国家自然科学基金、江苏省自然科学基金青年项目、面上项目以及企业横向项目等。主要从事有机合成化学、功能助剂的研制与开发（如萘系磺酸盐系列缩合物分散剂）。近年来，授权发明专利多项，在Organic Chemistry Frontiers、Organic Letters、Advanced Synthesis & Catalysis、《有机化学》、《现代农药》等国内外刊物上发表30多篇论文。

有机合成化学、

功能助剂的研制与开发（如萘系磺酸盐系列缩合物分散剂）

[25] Xianfang Hong, Jingcheng Guo, Jinhua Liu, Wei Cao, Chenlong Wei, Ye Zhang, Xiaoxiang Zhang & Zhenqian Fu*, “Organocatalytic dynamic kinetic resolution of N-arylindole lactams: atroposelective construction of axially chiral amino acids bearing a C-N chiral axis”, Sci. China Chem., 2022, 65, 905-911. .

[24] Ping Li, Boon Chong Lee, Xiaoxiang Zhang, Ming Joo Koh*, “Base-Mediated Site-Selective Hydroamination of Alkenes”, Synthesis, 2022, 54, 1566-1576.

[23] Ping Li, Fan Yang, Guiwen Hu, and Xiaoxiang Zhang*, “Palladium-Catalyzed One-Pot Synthesis of Pyrroloindolines from 2-Alkynyl Arylazides and Thioacetamides”, J. Org. Chem., 2021, 86, 10360.

[22] Fan Yang, Shijie Xu, Hui Fan, Xuechun Zhao, Xiaoxiang Zhang*, “One-Pot Synthesis of 2-Aminobenzophenones from 2-Alkynyl Arylazides Catalyzed by Pd and Cu Precursors”, Eur. J.Org. Chem., 2021, 86, 10360.

[21] Zhiqiang Zhou, Yao Xu, Boyu Zhu, Ping Li, Guiwen Hu, Fan Yang, Shijie Xu and Xiaoxiang Zhang*, “One-pot synthesis of 3-hydroxy-2-oxindoles via acyloin rearrangements of 2-hydroxy-indolin-3-ones generated in situ from 2-alkynyl arylazides”, New J. Chem., 2020, 44, 20303.

[20] Ping Li, Boyu Zhu, Yao Xu, Zhiqiang Zhou, Guiwen Hu, Fan Yang, Shijie Xu, Xiaoxiang Zhang*，“Palladium-catalyzed one-pot cycloaddition reactions of thioureas with 3H-indol-3-ones generated in situ from 2-alkynyl arylazides: rapid and efficient access to imidazoloindolines”, Org. Chem. Front., 2020, 7, 3480-3485.

[19] Ping Li, Rong Sheng, Zhiqiang Zhou, Guiwen Hu and Xiaoxiang Zhang*,“Synthesis of N-fused Seven-Membered Indoline-3-ones via Palladium-Catalyzed One-Pot Insertion Reaction from 2-Alkynyl Arylazides and Cyclic β-diketones”, Eur. J. Org. Chem., 2020, 14, 2146-2152.

[18] Rong Sheng, Ping Li, Zhiqiang Zhou, Guiwen Hu, Xiaoxiang Zhang*, “Pd-Catalyzed One-Pot Oxidation/Hydrolysis for the Synthesis of 2-Benzoylaminobenzoic Acids from 2-Alkynyl Arylazides”, Chin. J. Org. Chem., 2020, 40, 462-469.

[17] Yuanyuan Zhou, Xianxiao Chen, Dongliang Yin, Yuan Ling, Shifa Wang, Xiaoxiang Zhang and Weidong Rao*, “Gold-Catalyzed Cycloisomerization/Halogenation Sequence of 1,3-Enyne Esters with NXS: Efficient Synthesis of 5-Bromo/Iodo Cyclopentenones”, Eur. J. Org. Chem., 2019, 5, 999-1007.

[16] Ping Li, Wanxiong Yong, Rong Sheng, Weidong Rao, Xinbao Zhu and Xiaoxiang Zhang*, “Pd-catalyzed One-pot Insertion Reaction of Cyclic C-acylimines into Carbon–carbon σ-Bonds for the Synthesis of Polyfunctional Indolin-3-ones from 2-Alkynyl Arylazides and Aryl ketones”, Adv. Synth. Catal., 2019, 361, 201.

[15] Wanxiong Yong, Ping Li, Rong Sheng, Weidong Rao and Xiaoxiang Zhang*, “Pd-catalyzed One-pot Two-step Synthesis of 2-(1H-indol-3-yl)-2-phenylindolin-3-ones from 2-Alkynyl Arylazides and Indoles”, ChemistrySelect, 2018, 3, 11696-11699.

[14]Xiaoxiang Zhang*, Chang Lyu, Ping Li, Wanxiong Yong, Jing Li, Xinbao Zhu," Rapid Access to 4H-3,1-benzoxazin-4-ones via Gold-catalyzed One-pot Oxidative Rearrangement of 2-Alkynyl Arylazides ", Chin. J. Org. Chem., 2018, 38, 208-214.

[13] Xianxiao Chen，Yuanyuan Zhou，Mei Hong，Yuan Ling，Dongliang Yin，Shifa Wang，Xiaoxiang Zhang*, Weidong Rao*, “Gold(I)-Catalyzed Tandem Cycloisomerization and Fluorination of 1,3(4)-Enyne Esters with NFSI: One-Pot Assembly of 5-Fluoro- Cyclopentenones”, Adv. Synth. Catal., 2018, 360, 3700-3708.

[12]Xiaoxiang Zhang*, Ping Li, Chang Lyu, Wanxiong Yong, Jing Li, Xinyu Pan, Xinbao Zhu and Weidong Rao*," Palladium-Catalyzed One-Pot Synthesis of C2-Quaternary Indolin-3-ones via 1H-indole-3-sulfonates Generated in situ from 2-Alkynyl Arylazides and Sulfonic Acids", Adv. Synth. Catal., 2017, 359, 4175-4152.

[11] Cuili Chen, Xianxiao Chen, Xiaoxiang Zhang, Shifa Wang, Weidong Rao* and Philip Chan*, "Gold Catalyzed Dehydrogenative Cycloisomerization of 1,4-Enyne Esters to 3,5-Disubstituted Phenol Derivatives", Adv. Synth. Catal., 2017, 359, 4359.

[10] Xiaoxiang Zhang*, Ping Li, Chang Lyu, Wanxiong Yong, Jing Li, Xinbao Zhu and Weidong Rao*, "Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids ", Org. Biomol. Chem., 2017, 15, 6080-6083.

[9] Yongzhen Zou, Cuili Chen, Xianxiao Chen, Xiaoxiang Zhang*, Weidong Rao*. Silica Gel Mediated Friedel–Crafts Alkylation of 3-Indolylmethanols with Indoles: Synthesis of Unsymmetrical Bis(3-in-dolyl)methanes”, Eur. J. Org. Chem., 2017, 16, 2266-2271.

[8] Cuili Chen, Yongzhen Zoua, Xianxiao Chena, Xiaoxiang Zhang, Weidong Rao* and Philip Wai Hong Chan*, “Gold-Catalyzed Tandem 1,3-Migration/Double Cyclopropanation of 1-En-4,n-diyne Esters to Tetracyclodecene and Tetracycloundecene Derivatives”, Org. Lett., 2016, 18, 4730.

[7] Xiaoxiang Zhang*, Xiaoping Sun, Hui Fan, Chang Lyu, Ping Li, Haifei Zhang, Weidong Rao*, "Gold-catalyzed formation of Indole Derivatives from 2-Alkynyl Arylazides and Oxygen-Containing Heterocycles”, RSC Adv., 2016, 6, 56319-56322.

[6] Xiaoxiang Zhang*, Chang Lyu, Ping Li, Bo Fu, Weiwei Yao*, "Progress of the Research on the Lewis/Brønsted Acid-catalyzed Nucleophilic Substitution of Propargyl Alcohols", Chin. J. Org. Chem., 2016, 36, 1287.

[5] Ziping Cao*, Huaqing Zhang, Xiaoxiang Zhang, Ludan Zhang, Xin Meng, Guang Chen, Xian-En Zhao, Xuejun Sun, Jinmao You*, “Gold-catalyzed Tandem Cycloisomerization/Petasis-Ferrier Rearrangement: A Direct Route to 3-alkoxyindanones from Enynals and Alcohols”, RSC Adv., 2015, 5, 103155-103158.

[4] Xiaoxiang Zhang*, Xiaoping Sun, Jihui Tan, Hui Fan, Weidong Rao*, “Research Progress of Nucleophilic Substitution of Allylic Alcohols”, Chin. J. Org. Chem., 2015, 35, 2049-2058.

[3] Xiaoxiang Zhang*, Xiaoping Sun, Haifei Zhang, Xingli Cui, Mengtao Ma,“Gold-Catalyzed Tandem Reactions of 2-Alkynyl Arylazides and Carboxylic Acids for the Synthesis of 1H-Indol-3-yl Esters”, Chin. J. Org. Chem., 2015, 35, 1469-1474.

[2] Xiaoxiang Zhang*, Jing Wei Teo, Dik-Lung Ma, Chung-Hang Leung, Philip Wai Hong Chan*, “Ytterbium(III) Triflate-Catalyzed Annulation of Propargylic 1,4-Diols with Aryl Sulfonamides to Highly Substituted Pyrrole Derivatives”, Tetrahedron Lett., 2014, 55, 6703-6707.

[1] Xiaoxiang Zhang*, Wan Teng Teo, Weidong Rao, Dik-Lung Ma, Chung-Hang Leung, Philip Wai Hong Chan*, “Synthesis of Highly Substituted Indene Derivatives by Brønsted Acid Catalyzed Friedel-Crafts Reaction of Homo allylicAlcohols”, Tetrahedron Lett., 2014, 55, 3881-3884.

本科生课程：

精细有机合成

研究生课程：

精细化工实验新技术