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张葵       

 
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E-Mail:zhangkui@njfu.edu.cn
 
个人简况

副教授,江苏省“双创博士”,硕士生导师。

先后于南开大学获得硕士学位,于美国加州大学洛杉矶分校(UCLA)获得博士学位。

科研业绩:以通讯/第一作者在JACS、Nat. Commun.、JAFC、Chem Sci、Org Lett发表论文20多篇;主持/参与国家自然科学基金、江苏省自然科学基金以及多项企业横向课题。

学术服务:《香料香精化妆品》青年编委。

课题组主页:https://www.x-mol.com/groups/cai_lingchao1


工作经历
个人简况

副教授,江苏省“双创博士”,硕士生导师。

先后于南开大学获得硕士学位,于美国加州大学洛杉矶分校(UCLA)获得博士学位。

科研业绩:以通讯/第一作者在JACS、Nat. Commun.、JAFC、Chem Sci、Org Lett发表论文20多篇;主持/参与国家自然科学基金、江苏省自然科学基金以及多项企业横向课题。

学术服务:《香料香精化妆品》青年编委。

课题组主页:https://www.x-mol.com/groups/cai_lingchao1


研究方向
  • 香精香料的合成与提取

  • 林业抗真菌剂的开发

  • 绿色有机合成


学术成果

· Zhang, Z.; Xu, S.; Xu, L.; Lin, Y.; Lu, X.; Wang, N.; Cai, L.; Zhang, K.*"Photocatalytic Radical Relay Strategy for the Synthesis of Allylic gem-Difluorides via 1,4-Difunctionalization of gem-Difluorobuta-1,3-dienes", Org. Lett. 2026, 28, 1869.

· Zhang, K.; Chen, Y.; Zhang, X.; Cai, L.* "Synthesis of γ-Aminophosphonates via Photocatalytic Radical Relay Process", Org. Lett. 2026, 28, 774.

· Yao, X.; Yu, J.; Lin G.; Mei, H.; Zhang, K.;* Cai, L.*Photocatalytic Generation of Amidine Carbon Radicals for Aminodihydroquinoline Synthesis", Nat. Commun. 2025, 16,11547.

· Li, Y.; Li, K.; Zheng, X.; You, C.; Jin, J.; Cai, L.; Wang, F.; Zhang, K.* "Design, Synthesis, and Biological Evaluation of Novel Matrine Oxime Ester Derivatives", J. Agric. Food Chem. 2025, 73, 27204.

· Xu, Y.; Zhang, Z.; Wei, C.; Jin, J.; Zhang, K.*; Cai, L.* "Strategic Synthesis of γ-Nitroketones between Nitroalkanes and Cyclopropanols: Harnessing Free-Radical Nucleophilic Substitution for Chemical Innovation". Org. Lett., 2025, 27, 3111.

· Zhang, K.*; Liu, J.; Xu, Y.; Cai, L.* "Photocatalytic C(sp3)-P and C(sp2)-P Bond Formation via a Phosphorus Radical Cation", Org. Lett. 2024, 26, 9056.

· Gao, Y.; Li, Y.; Yan, W.; Zhang, K.*; Cai, L.*"Photoinduced Deconstructive Alkylation Approach Enabled by Oxy-Radicals from Alcohols", J. Org. Chem. 2024, 89, 14436.

· Wei, C.; Li, Y.; Yao, X.; Zhang, K.*; Cai, L.* "TFE-Facilitated Synthesis of Tetrahydropyridino[2,3-d]pyrimidine via Cascade [1,5]-Hydride Transfer/Cyclization", J. Org. Chem. 2023, 88, 17144.

·  Liu, J.; Jin, J.; Zhang, K.*; Cai, L. "Alkoxy Radical Induced Transformations from N-Alkoxyphthalimides Under the Photoredox Catalysis", Asian J. Org. Chem. 2023, 12, e202300160.

· Zhang, K.*; Cai, L.* "Enantioselective Hydroamination of Arylalkenes with Secondary Amines Via Cobalt Catalysis", Chem Catalysis 2023, 3, 100553.

· Zhang, K.; Chen, Y.; Song, L.; Cai, L.*"Progress of Catalytic Mitsunobu Reaction in the Two Decades", Asian J. Org. Chem. 2023, 12, e20200707.

· Zhang, K.; Wei, C.; Li, Y.; Yao, Y.; Song, L.; Jin, J.; Cai, L.* "Cu(OAc)2-Catalyzed Hydrazination of Cyclopropanols and Later-Stage Transformation to 4,5-Dihydropyrazoles", New J. Chem. 2023, 47, 3653.

· Zhang, K.; Cai, L.; Hong, S.; Kwon, O.* “Phosphine-Catalyzed α-Umpolung-Aldol Reaction for the Synthesis of Benzo[b]azapin-3-ones,” Org. Lett. 2019, 21, 5143.

· Zhang, K.#; Cai, L.#; Yang, Z.; Houk, K. H.; Kwon, O.* "Bridged [2.2.1] Bicyclic Phosphine Oxide Facilitates Catalytic γ-Umpolung-Wittig Olefination,”Chem. Sci. 2018, 9, 1867.

· Zhang, K.; Cai, L.; Jiang, X.; Garcia-Garibay, M. A.; Kwon, O.* “Phosphine-Mediated Iterative Arene Homologation Using Allenes,” J. Am. Chem. Soc. 2015, 137, 11258.


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